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250 L. Llorens et al. / Biochemical Systematics and Ecology 56 (2014) 246e254

Table 3
Chemical Composition [%] of Essential Oils of Thymus richardii samples from 18 Mediterranean populations.
Localities Bosnia 1 Bosnia 2 Sicily Ibiza Valencia Majorca
(Konnic/ (Borci/ (Marettimo) (Balearic (Spain) (Balearic
Spiljani) Bjelasnica) Islands) Islands)
a
b
Compounds KIE ) KIL ) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
a-Thujene 929 930 1.0 0.8 0.9 0.6 1.0 0.9 0.7 0.8 0.7 0.3 0.0 0.3 0.8 0.9 0.7 0.0 0.0 0.0
a-Pinene 937 939 1.0 1.0 1.0 0.4 0.7 1.2 1.5 1.3 1.2 0.8 0.7 2.2 0.9 1.5 1.3 0.0 0.0 0.0
Camphene 953 954 1.3 1.8 1.5 0.4 0.6 2.1 0.0 0.0 0.0 0.0 0.0 0.1 0.3 0.7 1.6 0.0 0.0 0.0
Sabinene 975 975 0.0 0.0 0.0 0.0 0.1 0.1 0.1 0.0 0.0 0.1 0.0 0.2 0.5 0.3 0.3 0.0 0.0 0.0
1-Octen-3-ol 983 979 0.2 0.2 0.2 0.0 0.2 0.3 0.1 0.2 0.0 0.2 0.0 0.2 0.3 0.3 0.5 0.0 0.0 0.0
3-Octanone 988 984 0.8 1.4 0.7 2.4 3.2 1.4 0.0 0.0 0.0 0.8 0.3 0.6 0.1 0.4 0.0 0.0 0.0 0.0
b-Myrcene 990 991 0.2 0.3 0.2 3.1 4.2 0.5 0.4 0.1 0.0 0.9 0.4 1.5 0.8 0.6 0.5 0.3 0.0 0.2
3-Octanol 993 991 0.0 0.0 0.0 0.0 0.0 0.0 2.1 0.8 0.6 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
a-Phellandrene 1006 1003 0.0 0.0 0.0 2.0 2.8 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Sylvestrene <iso> 1011 1009 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.6 0.0 0.0 0.0 0.0 0.0 0.0
a-Terpinene 1018 1017 0.2 0.2 0.2 0.2 0.5 0.4 0.4 0.7 0.4 0.7 0.2 0.5 0.6 0.4 0.2 0.0 0.0 0.1
p-Cymene 1028 1025 60.0 58.4 67.7 35.0 36.4 57.3 15.3 25.1 20.4 15.1 7.0 18.6 18.1 36.2 48.2 1.0 0.0 0.2
Limonene 1032 1029 0.3 0.3 0.4 0.0 0.8 0.4 16.7 8.8 13.0 1.6 0.5 1.3 4.9 4.4 0.6 0.0 0.0 0.0
1,8-Cineole 1035 1031 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.6 0.6 1.5 2.1 1.5 3.4 0.0 0.0 0.0
Benzene acetaldehyde 1045 1042 0.1 0.0 0.0 0.0 0.2 0.0 0.0 0.4 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.6
g-Terpinene 1061 1060 5.3 5.2 3.5 4.3 3.4 6.6 2.8 7.0 4.4 6.7 2.3 4.0 17.6 10.2 11.5 0.3 0.0 0.2
(Z)-Sabinene hydrate 1072 1070 0.6 0.4 0.4 0.8 0.5 0.5 0.9 1.2 0.7 0.0 0.0 0.0 10.4 5.1 2.2 0.0 0.0 0.0
Terpinolene 1090 1086 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.4 0.0 0.0 0.0 0.0 0.0 0.0
Linalool 1097 1097 0.1 0.0 0.0 0.0 0.0 0.0 2.2 1.7 1.0 0.0 0.0 0.2 1.7 1.1 4.8 0.2 0.1 0.4
(E)-Sabinene hydrate 1102 1098 0.2 0.1 0.2 0.1 0.4 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
(E)-Limonene oxyde 1138 1137 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Camphor 1150 1146 0.3 0.3 0.2 0.1 0.2 1.0 0.0 0.9 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.1
1-Terpinen-4-ol 1182 1177 1.2 2.6 2.3 1.6 0.9 2.0 0.6 0.4 0.3 0.1 0.0 0.0 0.7 1.5 4.0 0.3 0.4 0.4
p-Cymen-8-ol 1188 1183 0.3 0.3 0.3 0.2 0.4 0.3 0.0 0.0 0.0 0.9 0.7 0.8 1.2 0.9 1.0 0.0 0.0 0.0
a-Terpineol 1193 1189 0.6 0.6 0.5 0.5 0.5 0.5 0.0 0.0 0.0 0.3 0.1 0.4 0.0 0.1 0.1 0.0 0.0 0.0
(Z)-Dihydrocarvone 1195 1193 0.0 0.0 0.0 0.0 0.0 0.0 0.6 0.0 0.1 0.2 0.1 0.2 0.0 0.0 0.0 0.0 0.0 0.0
(E)-Dihydrocarvone 1202 1201 0.0 0.0 0.0 0.0 0.0 0.0 5.7 0.0 2.5 0.2 0.0 0.1 0.1 0.1 0.2 0.0 0.0 0.3
(E)-Carveol 1218 1217 0.0 0.0 0.0 0.0 0.0 0.0 0.7 0.0 0.0 0.5 0.4 0.5 0.0 0.0 0.0 0.0 0.0 0.0
Methyl thymol 1232 1232 16.8 14.1 10.5 13.0 9.6 13.8 8.8 2.4 14.9 0.0 0.0 0.0 0.0 0.0 0.0 8.0 10.9 10.3
Methyl carvacrol 1246 1240 0.0 1.0 0.1 3.5 3.8 0.1 0.0 0.0 0.0 13.9 18.9 14.6 0.0 0.0 0.0 0.5 0.1 1.7
Thymoquinone 1256 1252 0.1 0.0 0.0 0.1 0.3 0.0 0.4 0.1 0.1 0.0 0.0 0.1 0.3 0.9 0.0 0.0 0.0 0.0
Bornyl acetate 1291 1289 0.4 0.8 0.2 0.0 0.0 0.6 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Thymol 1294 1290 4.0 3.9 2.8 21.6 21.8 3.8 1.5 13.9 2.8 14.7 6.5 4.9 18.1 12.8 1.5 11.4 9.0 6.2
Carvacrol 1305 1299 0.1 0.0 0.4 0.2 0.5 0.3 15.2 0.0 8.0 12.8 10.8 9.8 0.1 5.2 0.0 6.4 10.5 5.2
Thymol acetate 1356 1352 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0
a-Copaene 1380 1377 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.5 0.3 0.0 0.0 0.0 0.0 0.0 0.0
b-Bourbonene 1387 1388 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.8 0.0 0.1 0.0 0.0 0.0 0.2 0.5 0.4 0.3 1.0
b-Caryophyllene 1424 1419 1.8 2.7 2.3 4.0 1.9 2.5 0.4 2.6 1.1 6.1 12.0 10.2 4.8 3.2 4.5 5.8 7.2 7.3
(E)-a-Bergamotene 1436 1435 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.3
a-Humulene 1456 1455 0.0 0.0 0.0 0.0 0.1 0.0 0.0 0.3 0.3 0.2 0.3 0.3 0.0 0.0 0.0 0.0 0.3 0.1
b-Farnesene 1458 1457 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.7 1.4 1.4 0.0 0.0 0.0 0.7 0.8 0.9
Germacrene-D 1485 1485 0.0 0.0 0.0 0.0 0.0 0.0 0.3 6.9 1.2 0.6 2.8 1.3 0.7 0.8 1.2 1.5 1.2 2.2
(E)-Methyl isoeugenol 1498 1492 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.1 0.0 0.0 0.0 0.0 0.0 0.0
a-Selinene 1503 1498 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2.1 1.9 1.3 0.0 0.0 0.0
b-Bisabolene 1509 1506 0.6 0.9 1.0 1.1 0.9 0.2 16.4 17.7 17.6 12.3 15.9 9.6 0.1 0.2 0.3 40.2 43.4 44.3
d-Amorphene 1514 1512 0.0 0.0 0.0 0.0 0.0 0.0 0.6 0.8 1.4 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
d-Cadinene 1525 1523 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.3 0.3 0.0 0.4 0.3 0.0 0.0 0.0 0.6 0.6 0.7
b-Sesquiphellandrene 1526 1523 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.7 0.5 0.0 0.0 0.0 0.0 0.0 0.0
(E)-Calamenene 1529 1529 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.4 0.4 0.2 0.0 0.0 0.0
a-Cadinene 1539 1539 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.2 0.3
Elemol 1552 1550 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Germacrene D-4-ol 1576 1576 0.0 0.0 0.0 0.4 0.4 0.0 0.4 0.0 0.6 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Caryophyllene oxyde 1584 1583 2.3 2.6 2.1 3.3 2.7 2.4 0.4 1.2 0.8 0.2 6.1 4.8 2.2 1.9 3.1 6.2 4.3 4.5
b-Atlantol 1610 1608 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.2 0.2 1.3 1.9 1.1 0.0 0.0 0.0 0.4 0.2 0.2
Cubenol<1,10-di-epi> 1619 1619 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.1 0.7 0.5 4.0 2.5 2.6
Eudesmol <10-epi-g> 1626 1624 0.0 0.0 0.0 0.0 0.0 0.0 0.4 0.2 0.4 0.0 0.0 0.0 0.0 0.0 0.0 0.4 0.1 0.1
t-Cadinol 1649 1646 0.1 0.0 0.1 0.1 0.0 0.2 1.4 1.7 3.3 0.6 0.6 0.3 8.0 5.1 3.9 0.1 0.2 0.3
a-Cadinol 1657 1654 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.7 0.0 0.3 0.0 0.0 0.0 0.0 0.0 0.0
Eudesmol <7-epi-a-> 1668 1664 0.0 0.0 0.0 0.0 0.0 0.0 0.3 0.0 0.4 0.0 0.3 0.0 0.0 0.0 0.0 0.2 0.0 0.0
Bisabolol < epi-a-> 1683 1685 0.1 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.2 0.8 0.9 0.5 0.0 0.0 0.0 1.3 0.5 0.4
Eudesma-4(15),7-dien-1-b-ol 1692 1688 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.2 0.0 0.5 0.6 0.5 0.0 0.0 0.0 3.1 1.5 1.9
Hexadecanoic acid 1980 1960 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.5 0.1 0.1
Monoterpene compounds 93.9 92.1 93.3 87.5 89.3 92.4 74.3 64.5 70.4 71.7 49.0 62.9 79.4 84.4 82.1 28.4 30.9 25.2
Monoterpene aliphatic hydrocarbons 9.2 9.6 7.7 11.0 14.0 12.2 22.5 18.7 19.6 11.4 4.0 11.1 26.5 19.1 16.7 0.6 0.0 0.5
Monoterpene aromatic hydrocarbons 60.0 58.4 67.7 35.0 36.4 57.3 15.3 25.1 20.4 15.1 7.0 18.6 18.1 36.2 48.2 1.0 0.0 0.2
Oxygenated monoterpenes 24.7 24.1 17.9 41.5 38.9 22.9 36.5 20.7 30.4 45.2 38 33.2 34.8 29.1 17.2 26.8 30.9 24.5

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